2025
- Regio- and Enantioconvergent Hydroallylation of Acrylates Enabled by γ-Silyl-Substituted Allyl AcetatesAngew. Chem., Int. Ed. 2025, 64, e202425256; (Communication) DOI: 10.1002/anie.202425256Highlighted in SYNFACTS
2024
- Rhodium-Catalyzed Decarbonylative Intramolecular Arylation of 2-(1H-Indole-1-carbonyl)benzoic AcidsSynlett 2024, 35, 2037–2041; (Communication) DOI: 10.1055/a-2278-5797
- Modular Synthesis of 3,3-Disubstituted Oxindoles from Nitrones and Acrylic AcidsOrg. Biomol. Chem. 2024, 22, 6282–6287; (Communication) DOI: 10.1039/D4OB00964A
- Palladium-Catalyzed anti-Michael-Type Hydroamination of N-(Quinolin-8-yl)acrylamide with 2-PyridonesOrg. Lett. 2024, 26, 6444–6448; (Communication) DOI: 10.1021/acs.orglett.4c02234
- Palladium-Catalyzed anti-Michael-Type (Hetero)arylation of AcrylamidesJ. Am. Chem. Soc. 2024, 146, 13697–13702; (Communication) DOI: 10.1021/jacs.4c00841
- Rhodium-Catalysed Additive-Free Alkoxycarbonylation of Indoles: 2,4,6-Trimethylbenzoic Acid-Based Carbonate Anhydrides as a Versatile Alkoxycarboxyl SourceOrg. Biomol. Chem. 2024, 22, 3209–3214; (Communication) DOI: 10.1039/D4OB00205A
- Rhodium-Catalysed Additive-Free Carbonylation of Benzamides with Diethyl Dicarbonate as a Carbonyl SourceOrg. Biomol. Chem. 2024, 22, 2744–2748; (Communication) DOI: 10.1039/D4OB00059EHighlighted in SYNFACTS
2023
- Rhodium-Catalyzed Intramolecular Acylation of 2-(Indol-1-yl)benzoic Acids under Redox-Neutral ConditionsSynlett 2023, 34, 1894–1898; (Communication) DOI: 10.1055/a-2088-9106
- Diastereo- and Enantioselective Reductive Mannich-type Reaction of α,β-Unsaturated Carboxylic Acids to Ketimines: A Direct Entry to Unprotected β2,3,3-Amino AcidsChem. Eur. J. 2023, 29, e202202575; (Article) DOI: 10.1002/chem.202202575
2022
- Rhodium-Catalyzed C6-Selective Alkoxycarbonylation of PyridonesChem. Lett. 2022, 51, 775–777; (Communication) DOI: 10.1246/cl.220194
- Rhodium-Catalysed Decarbonylative C(sp2)–H Alkylation of Indolines with Alkyl Carboxylic Acids and Carboxylic Anhydrides under Redox-Neutral ConditionsOrg. Biomol. Chem. 2022, 20, 2808–2812; (Communication) DOI: 10.1039/D2OB00249C
- Rhodium-Catalyzed C(sp2)–H Alkoxycarbonylation/Acylation of Indolines with Anhydrides as a Carbonyl SourceOrg. Lett. 2022, 24, 1141–1145; (Communication) DOI: 10.1021/acs.orglett.1c04195
- Copper-Catalyzed Enantioselective Reductive Aldol Reaction of α,β-Unsaturated Carboxylic Acids to Ketones: Silanes as Activator and Transient Protecting GroupChem. Eur. J. 2022, 28, e202104273; (Article) DOI: 10.1002/chem.202104273Highlighted in SYNFACTS
2021
- Rhodium-Catalyzed Additive-Free C–H Ethoxycarbonylation of (Hetero)Arenes with Diethyl Dicarbonate as a CO SurrogateEur. J. Org. Chem. 2021, 4938–4942; (Communication) DOI: 10.1002/ejoc.202100956
2020
- Dealkoxylation of N-Alkoxyamides without an External Reductant Driven by Pd/Al Cooperative CatalysisOrg. Biomol. Chem. 2020, 18, 7545–7548; (Communication) DOI: 10.1039/D0OB01815E
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Synthesis of Unsymmetrical Benzils via Palladium-Catalysed α-Arylation–Oxidation of 2-Hydroxyacetophenones with Aryl BromidesOrg. Biomol. Chem. 2020, 18, 3679–3683; (Article) DOI: 10.1039/D0OB00575D
Ruthenium-Catalysed Cyclisation Reactions of 1,11-Dien-6-ynes Leading to BiindenesOrg. Biomol. Chem. 2020, 18, 1760–1764; (Article) DOI: 10.1039/D0OB00179A
Rhodium(I)-Catalyzed Arylative Annulation of β-Alkynyl Ketones for Preparation of Fused AromaticsEur. J. Org. Chem. 2020, 306–310; (Article) DOI: 10.1002/ejoc.2019014812018- Synthesis of Fused and Linked Benzofurans from 2-Alkynylphenol Derivatives through Rhodium(I)-Catalyzed Domino-Type Addition ReactionsChimia 2018, 72, 888–891; (Article) DOI: 10.2533/chimia.2018.888
- Silver-Catalyzed Ring-Opening [3 + 2] Annulation of Cyclopropenones with AmidesNew J. Chem. 2018, 42, 19178–19182; (Article) DOI: 10.1039/C8NJ04579H
- Synthesis of Indole-Fused Heteroacenes by Cascade Cyclisation Involving Rhodium(II)-Catalysed Intramolecular C–H AminationOrg. Biomol. Chem. 2018, 16, 6703–6707; (Article) DOI: 10.1039/C8OB01837EHighlighted in SYNFACTS
- Synthesis of Trisubstituted 1,3-Oxazin-6-ones via Base-Catalyzed Ring-Opening Annulation of Cyclopropenones with N-(Pivaloyloxy)amidesTetrahedron Lett. 2018, 59, 1458–1460; (Communication) DOI: 10.1016/j.tetlet.2018.02.084
- Palladium-Catalyzed Ring-Opening Coupling of Cyclobutenols with Aryl HalidesSynlett 2018, 29, 754–758; (Communication) DOI: 10.1055/s-0036-1589117
2017- Rh-Catalyzed Carbonylation of (2-Pyridylmethylene)cyclobutanesChem. Lett. 2017, 46, 1721–1723; (Communication) DOI: 10.1246/cl.170830
2016- Rhodium(I)-Catalysed Skeletal Reorganisation of Benzofused Spiro[3.3]heptanes via Consecutive Carbon–Carbon Bond CleavagesOrg. Biomol. Chem. 2016, 14, 7024–7027; (Article) DOI: 10.1039/C6OB01344A
- Rhodium-Catalyzed Cycloisomerization of 2-Alkynyl-N′-arylidenebenzohydrazides through exo-CarboaminationAsian J. Org. Chem. 2016, 5, 891–894; (Communication) DOI: 10.1002/ajoc.201600155
- Rhodium(I)-Catalysed Intermolecular Alkyne Insertion into (2-Pyridylmethylene)cyclobutenesOrg. Biomol. Chem. 2016, 14, 5023–5027; (Communication) DOI: 10.1039/C6OB00734A
- Ruthenium-Catalyzed Cycloisomerization of 2,2′-Diethynylbiphenyls Involving Cleavage of a Carbon–Carbon Triple BondChem. Eur. J. 2016, 22, 1941–1943; (Communication) DOI: 10.1002/chem.201504937
2015- Oxidative Cyclization of Dialdehydes with Alcohols and 1,3-Dicarbonyl Compounds under Rh(III)/Cu(II) ConditionsTetrahedron 2015, 71, 9264–9270; (Article) DOI: 10.1016/j.tet.2015.10.034
- Reactions of Three-Membered Ring CompoundsIn Cleavage of Carbon–Carbon Single Bonds by Transition Metals; Murakami, M.; Chatani, N. Eds.; Wiley-VCH: 2015; Chapter 2, pp 35–88; (Book chapter) DOI: 10.1002/9783527680092.ch2
- Reactions of Four-Membered Ring CompoundsIn Cleavage of Carbon–Carbon Single Bonds by Transition Metals; Murakami, M.; Chatani, N. Eds.; Wiley-VCH: 2015; Chapter 3, pp 89–118; (Book chapter) DOI: 10.1002/9783527680092.ch3
- Rhodium-Catalyzed Addition/Spirocyclization of Arylboronic Esters Containing β-Aryl α,β-Unsaturated Ester MoietySynlett 2015, 26, 1233–1237; (Communication) DOI: 10.1055/s-0034-1378691
- Rhodium(III)-Catalyzed [2+2+2] Cyclotrimerization of Diynes with Maleic Anhydrides as Alkyne EquivalentsEur. J. Org. Chem. 2015, 3032–3035; (Communication) DOI: 10.1002/ejoc.201500252
- A Rhodium(I)-Catalysed Formal Intramolecular C–C/C–H Bond MetathesisChem. Commun. 2015, 51, 7393–7396; (Communication) DOI: 10.1039/C5CC01415H
- Synthesis of 2-Acyl-1-naphthols by Gold-Catalyzed Oxidative Cyclization of 2-Alkenylphenyl Alkynyl KetonesTetrahedron 2015, 71, 869–874; (Article) DOI: 10.1016/j.tet.2014.12.041
- Rhodium-Catalysed Arylative Annulation of 1,4-Enynes with Arylboronic AcidsOrg. Biomol. Chem. 2015, 13, 702–705; (Communication) DOI: 10.1039/C4OB02210F
2014- Rhodium(III)-Catalysed Decarbonylative Coupling of Maleic Anhydrides with AlkynesRSC Adv. 2014, 4, 37138–37141; (Communication) DOI: 10.1039/C4RA06452F
- Rhodium-Catalyzed Arylation of Acylsilanes with Sodium TetraarylboratesJ. Organomet. Chem. 2014, 765, 64–67; (Communication) DOI: 10.1016/j.jorganchem.2014.05.005
- Rhodium(III)-Catalyzed Synthesis of Indoles from 1-Alkylidene-2-arylhydrazines and Alkynes via C–H and N–N Bond CleavagesTetrahedron Lett. 2014, 55, 3302–3304; (Communication) DOI: 10.1016/j.tetlet.2014.04.016
- Gold(I)-Catalyzed Ring-Expanding Spiroannulation of Cyclopropenones with EnynesJ. Org. Chem. 2014, 79, 2739–2745; (Note) DOI: 10.1021/jo500045n
- Cyclobutene Ring Opening ReactionsIn Comprehensive Organic Synthesis II; Knochel, P.; Molander, G. A. Eds.; Elsevier: 2014; Volume 5, Chapter 16, pp 732–782; (Book chapter) DOI: 10.1016/B978-0-08-097742-3.00517-6
2013- Rhodium-Catalyzed Cross-Coupling of Alkenyl Halides with Arylboron CompoundsAdv. Synth. Catal. 2013, 355, 3396–3400; (Communication) DOI: 10.1002/adsc.201300482
- Synthesis of Heterocycles via X–H Bond Addition to DiynesIn Transition-Metal-Mediated Aromatic Ring Construction; Tanaka, K. Ed.; John Wiley & Sons: 2013; Chapter 20, pp 537–547; (Book chapter) DOI: 10.1002/9781118629871.ch20
- Palladium-Catalyzed Ring-Opening Alkynylation of CyclopropenonesEur. J. Org. Chem. 2013, 4219–4222; (Communication) DOI: 10.1002/ejoc.201300220
- Azulenophenanthrenes from 2,2′-Di(arylethynyl)biphenyls through C–C Bond Cleavage of a Benzene RingAngew. Chem., Int. Ed. 2013, 52, 6492–6495; (Communication) DOI: 10.1002/anie.201300570Highlighted in SYNFACTS
- Synthesis of Tetrasubstituted Benzenes via Rhodium(I)-Catalysed Ring-Opening Benzannulation of Cyclobutenols with AlkynesOrg. Biomol. Chem. 2013, 11, 3424–3427; (Communication) DOI: 10.1039/C3OB40436F
- Synthesis of Dibenzoheteropines of Group 13–16 Elements via Ring-Closing MetathesisJ. Org. Chem. 2013, 78, 3329–3335; (Article) DOI: 10.1021/jo4001993
- Synthesis of Phthalazinones via Palladium(II)-Catalysed Intramolecular Oxidative C–H/C–H Cross-Coupling of N′-MethylenebenzohydrazidesOrg. Biomol. Chem. 2013, 11, 2084–2087; (Communication) DOI: 10.1039/C3OB40195BHighlighted in SYNFACTS
2012- Rhodium-Catalysed Intramolecular trans-Bis-Silylation of Alkynes to Synthesise 3-Silyl-1-benzosilolesOrg. Biomol. Chem. 2012, 10, 3175–3177; (Communication) DOI: 10.1039/C2OB25242B
- Double 1,4-Rhodium Migration Cascade in Rhodium-Catalysed Arylative Ring-Opening/Spirocyclisation of (3-Arylcyclobutylidene)acetatesChem. Commun. 2012, 48, 2988–2990; (Communication) DOI: 10.1039/C2CC18098G
2011- Rhodium-Catalyzed Double 1,4-Addition of Arylboronic Acids to β-Aryloxyacrylates Involving β-Oxygen EliminationAdv. Synth. Catal. 2011, 353, 1923–1926; (Communication) DOI: 10.1002/adsc.201100253
- Homocoupling of Arylboronic Acids Catalyzed by Simple Gold SaltsTetrahedron Lett. 2011, 52, 4779–4781; (Communication) DOI: 10.1016/j.tetlet.2011.07.030
- Palladium-Catalyzed Hydrometalation and Bismetalation of BiphenyleneOrganometallics 2011, 30, 3923–3925; (Communication) DOI: 10.1021/om200436d
- Gold-Catalysed Alkenyl- and Arylsilylation Reactions Forming 1-SilaindenesChem. Commun. 2011, 47, 8697–8699; (Communication) DOI: 10.1039/C1CC12457A
- Synthesis of Siloles via Rhodium-Catalyzed Cyclization of Alkynes and Diynes with HexamethyldisilaneSynlett 2011, 813–816; (Communication) DOI: 10.1055/s-0030-1259914
- Synthesis of Pyrenes by Twofold Hydroarylation of 2,6-DialkynylbiphenylsChem. Lett. 2011, 40, 40–41; (Communication) DOI: 10.1246/cl.2011.40
- Metal-Catalysed Cleavage of Carbon–Carbon BondsChem. Commun. 2011, 47, 1100–1105; (Review) DOI: 10.1039/C0CC02566FTop ten most accessed articles in October (2010)
Below is a list of publication on research at Kyoto University.
2010- Hydrosilylation–Metathesis Sequence Leading to 1-SilaindenesSynlett 2010, 2743–2746; (Communication) DOI: 10.1055/s-0030-1258816Highlighted in SYNFACTS
- Ruthenium-Catalyzed trans-Hydrogermylation of Alkynes: Formation of 2,5-Disubstituted Germoles through Double trans-Hydrogermylation of 1,3-DiynesOrg. Lett. 2010, 12, 1056–1058; (Communication) DOI: 10.1021/ol1000445
2008- Palladium-Catalyzed Sequential Carbon–Carbon Bond Cleavage/Formation Producing Arylated BenzolactonesOrg. Lett. 2008, 10, 5219–5221; (Communication) DOI: 10.1021/ol802218a
- Gold-Catalysed Intramolecular trans-Allylsilylation of Alkynes Forming 3-Allyl-1-silaindenesChem. Commun. 2008, 2744–2746; (Communication) DOI: 10.1039/B804721ASelected as Hot Article
- Synthesis of Silole Skeletons via Metathesis ReactionsSynlett 2008, 561–564; (Communication) DOI: 10.1055/s-2008-1032096
2007- Rhodium-Catalyzed Carbonylation of SpiropentanesJ. Am. Chem. Soc. 2007, 129, 12596–12597; (Communication) DOI: 10.1021/ja0732779
- Asymmetric Synthesis of 3,4-Dihydrocoumarins by Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanonesJ. Am. Chem. Soc. 2007, 129, 12086–12087; (Communication) DOI: 10.1021/ja075141gHighlighted in SYNFACTS
- Ruthenium-Catalysed Double trans-Hydrosilylation of 1,4-Diarylbuta-1,3-diynes Leading to 2,5-DiarylsilolesChem. Commun. 2007, 2627–2629; (Communication) DOI: 10.1039/B703397D
- Rhodium-Catalyzed Reactions of Cyclobutanones with Alcohols and Amines Forming Esters and AmidesChem. Lett. 2007, 36, 744–745; (Communication) DOI: 10.1246/cl.2007.744
- Synthesis of Silafluorenes by Iridium-Catalyzed [2 + 2 + 2] Cycloaddition of Silicon-Bridged Diynes with AlkynesOrg. Lett. 2007, 9, 133–136; (Communication) DOI: 10.1021/ol062732nHighlighted in SYNFACTS
- C–E Bond Formation through Element–Element Addition to Carbon–Carbon Multiple BondsIn Comprehensive Organometallic Chemistry III; Crabtree, R. H.; Mingos, D. M. P. Eds.; Elsevier: 2007; Vol. 10, pp 725–787; (Book chapter) DOI: 10.1016/B0-08-045047-4/00138-2
2006- Construction of Carbon Frameworks through β-Carbon Elimination Mediated by Transition MetalsBull. Chem. Soc. Jpn. 2006, 79, 1315–1321; (Account) DOI: 10.1246/bcsj.79.1315
- Synthesis of 3-Acyl-4-alkenylpyrrolidines by Platinum-Catalyzed Hydrative Cyclization of AllenynesHelv. Chim. Acta 2006, 89, 1672–1680; (Article) DOI: 10.1002/hlca.200690165
- Two-Carbon Ring Expansion of Cyclobutanone Skeletons by Nickel-Catalyzed Intermolecular Alkyne InsertionTetrahedron 2006, 62, 7540–7546; (Article) DOI: 10.1016/j.tet.2006.03.118
- Enantioselective C–C Bond Cleavage Creating Chiral Quaternary Carbon CentersOrg. Lett. 2006, 8, 3379–3381; (Communication) DOI: 10.1021/ol061359g
- Torque Control by Metal-Orbital InteractionsPure Appl. Chem. 2006, 78, 415–423; (Proceeding) DOI: 10.1351/pac200678020415
- Eight-Membered Ring Construction by [4+2+2] Annulation Involving β-Carbon EliminationJ. Am. Chem. Soc. 2006, 128, 2166–2167; (Communication) DOI: 10.1021/ja0552895
- A Direct Entry to Bicyclic Cyclobutenes via Platinum-Catalyzed Cycloisomerization of AllenynesSynlett 2006, 575–578; (Communication) DOI: 10.1055/s-2006-932482
- Activation of a Cyclobutanone Carbon–Carbon Bond over an Aldehyde Carbon–Hydrogen Bond in the Rhodium-Catalyzed DecarbonylationChem. Lett. 2006, 35, 288–289; (Communication) DOI: 10.1246/cl.2006.288
2005- Synthesis of 1H-Inden-1-ol Derivatives via Rhodium-Catalyzed Annulation of o-Acylphenylboronic Acids with AlkynesChem. Lett. 2005, 34, 1416–1417; (Communication) DOI: 10.1246/cl.2005.1416
- Molybdenum-Catalyzed Ring-Closing Metathesis of AllenynesOrg. Lett. 2005, 7, 3953–3956; (Communication) DOI: 10.1021/ol0514348
- Addition/Ring-Opening Reaction of Organoboronic Acids to Cyclobutanones Catalyzed by Rhodium(I)/P(t-Bu)3 ComplexBull. Chem. Soc. Jpn. 2005, 78, 1528–1533; (Article) DOI: 10.1246/bcsj.78.1528
- Synthesis of Seven-Membered Ring Ketones by Arylative Ring-Expansion of Alkyne-Substituted CyclobutanonesAngew. Chem. Int. Ed. 2005, 44, 4608–4611; (Communication) DOI: 10.1002/anie.200500799Selected as VIP
- Nickel-Catalyzed Intermolecular Alkyne Insertion into CyclobutanonesJ. Am. Chem. Soc. 2005, 127, 6932–6933; (Communication) DOI: 10.1021/ja050674f
- Acids Direct 2-Styrylcyclobutanone into Two Distinctly Different Reaction PathwaysOrg. Lett. 2005, 7, 2059–2061; (Communication) DOI: 10.1021/ol0506922
- Contrasteric Stereochemical Dictation of the Cyclobutene Ring-Opening Reaction by a Vacant Boron p OrbitalJ. Am. Chem. Soc. 2005, 127, 1366–1367; (Communication) DOI: 10.1021/ja043979n
2004- Dramatic Effects of Boryl Substituents on Thermal Ring-Closing Reaction of VinylallenesJ. Am. Chem. Soc. 2004, 126, 10838–10839; (Communication) DOI: 10.1021/ja046429y
- Eight-Membered Ring Formation via Olefin Insertion into a Carbon–Carbon Single BondChem. Lett. 2004, 33, 876–877; (Communication) DOI: 10.1246/cl.2004.876
- Stereoselective Synthesis of (Z)-1-Silyl-2-stannylethene by Palladium-Catalyzed Silastannation of Ethyne and Its Synthetic TransformationsSynthesis 2004, 1522–1526; (Article) DOI: 10.1055/s-2004-822405
- Rhodium-Catalyzed Addition/Ring-Opening Reaction of Arylboronic Acids with CyclobutanonesOrg. Lett. 2004, 6, 1257–1259; (Communication) DOI: 10.1021/ol049833a
- Cycloadditions of AllenesIn Modern Allene Chemistry; Klause, N., Hashmi, A. S. K., Eds.; Wiley-VCH: 2004; Chapter 12, pp 7277–815; (Book chapter) DOI: 10.1002/9783527619573.ch12
2002- Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective (E)-Allylsilane Formation via C–C Bond CleavageOrganometallics 2002, 21, 1537–1539; (Communication) DOI: 10.1021/om020007k
2000- Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C–C Bond CleavageJ. Am. Chem. Soc. 2000, 122, 11015–11016; (Communication) DOI: 10.1021/ja002885k
- Convenient Preparation of SilylboranesOrganometallics 2000, 19, 4647–4649; (Note) DOI: 10.1021/om000254t
1999- Stereoselective 1,4-Silaboration of 1,3-Dienes Catalyzed by Nickel ComplexesOrg. Lett. 1999, 1, 1567–1569; (Communication) DOI: 10.1021/ol990908y
- Regio- and Stereoselective Synthesis of (Z)-β-Silylalkenylboranes by Silaboration of Alkynes Catalyzed by Palladium and Platinum ComplexesTetrahedron 1999, 55, 8787–8900; (Article) DOI: 10.1016/S0040-4020(99)00444-5
1998- Nickel-Catalyzed Silaborative Dimerization of AlkynesOrganometallics 1998, 17, 5233–5235; (Communication) DOI: 10.1021/om9807250
- Platinum-Catalyzed Silaborative Coupling of 1,3-Dienes to Aldehydes: Regio- and Stereoselective Allylation with Dienes through Allylic Platinum IntermediatesJ. Am. Chem. Soc. 1998, 120, 4248–4249; (Communication) DOI: 10.1021/ja980373o