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土戸良高 業績 / PUBLICATION LIST

論 文   総説・解説・記事   受 賞


2025

33'. Orthogonal Dynamic Metal-Templated Synthesis of Fully π-Conjugated [2]Catenane with Switchable Mechanical Chirality
Hiromichi Yokoyama, Miki Kawata, Masahiro Hayakawa, Takuji Hatakeyama, Hidetoshi Kawai, Yoshitaka Tsuchido,* Tomohito Ide*
ChemRxiv, 10.26434/chemrxiv-2025-0d4h3 (2025).

32. Synthesis and Chiroptical Properties of Chiral Helical Foldamers Based on Highly Fluorescent Dibenzopyrrolo[1,2-a][1,8]naphthyridines Linked to a Tetraphenylene Core
Kotaro Matsumura, Masashi Hasegawa, Yoshitaka Tsuchido, Hidetoshi Kawai*
Asian J. Org. Chem., 14(7), e202500409 (2025).
Special Collection 'In Memory of Professor Masahiko Iyoda'
Selected as "Cover Feature"

31. Optical Axial Chirality Enhancement and Transfer within Aromatic Micelles upon (Co-)encapsulation
Tomohiro Yasuda, Yoshihisa Hashimoto, Yuya Tanaka,* Daiki Tauchi, Masashi Hasegawa, Yusuke Kurita, Hidetoshi Kawai, Yoshitaka Tsuchido,* Michito Yoshizawa*
JACS Au, 5(2), 586-592, (2025).

30. Aromatic Ring-Fused Amidine Based Allosteric Receptors Activated by Guest-Induced π-Conjugation Switching
Takayuki Kataoka, Kotaro Matsumura, Kosuke Ono, Yoshitaka Tsuchido, Hidetoshi Kawai*
ChemPlusChem, 90(1), e202400612 (2025).

2024

29. A Water-Soluble Cycloparaphenylene: Supramolecular Receptor with Visible Fluorescence
Ryo Morito, Takayuki Kataoka, Kunio Saito, Kohtaro Osakada, Tomohito Ide, Yoshitaka Tsuchido,* Hidetoshi Kawai*
ChemistryEurope, 2(6), e202400025 (2024).
Selected as "Editor's Choice: Spotlights"
          
29'. A Water-Soluble Cycloparaphenylene: Synthesis and Application as a Supramolecular Receptor with Visible Fluorescence
Ryo Morito, Takayuki Kataoka, Kunio Saito, Kohtaro Osakada, Tomohito Ide, Yoshitaka Tsuchido,* Hidetoshi Kawai*
ChemRxiv, 10.26434/chemrxiv-2024-0c1s7 (2024).

28. M/P Helicity Switching and Chiral Amplification in Double-Helical Monometallofoldamers
Kotaro Matsumura, Keigo Kinjo, Kotaro Tateno, Kosuke Ono, Yoshitaka Tsuchido, Hidetoshi Kawai*
J. Am. Chem. Soc., 146, 21078-21088 (2024).
Tokyo Univ. Sci. Press Release

27. Synthesis and Chiroptical Properties of Cyclic Anthraquinodimethane Dimer Using Au-Templated Method
Soichiro Sugiyama, Kazuharu Murotani, Fumitaka Ishiwari, Akinori Saeki, Hidetoshi Kawai, Takanori Suzuki, Yoshitaka Tsuchido,* Yusuke Ishigaki*
Chem. Lett., 53(6), upae102 (2024).

26. Umbrella-Shaped Amphiphiles: Internal Alkylation of an Aromatic Micelle and Its Impact on Cavity Features
Masaya Endo, Shinji Aoyama, Yoshitaka Tsuchido, Lorenzo Catti, Michito Yoshizawa*
Angew. Chem. Int. Ed., 63(26), e202404088, (2024).

25. Recognition of Amino Acid Salts by Temperature-Dependent Allosteric Binding with Stereodynamic Urea Receptors
Yuki Kimura, Kotaro Matsumura, Kosueke Ono, Yoshitaka Tsuchido, Hidetoshi Kawai*
Chem. Eur. J., 30(29), e202400154 (2024).

2023

24. A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure
Naoki Narita, Yusuke Kurita, Kohtaro Osakada, Tomohito Ide,* Hidetoshi Kawai,* YoshitakaTsuchido*
Nature Communications, 14, 8091 (2023).
Highlighted in Synfacts, 20, 363 (2024) by D. Zhao and Z. Liu

2022

24'. A Dodecamethoxy [6]Cycloparaphenylene Consisting Entirely of Hydoroquinone Ether Units: Redox Properties and Host-Guest Complexation
Naoki Narita, Yusuke Kurita, Kohtaro Osakada, Tomohito Ide,* YoshitakaTsuchido,* Hidetoshi Kawai*
ChemRxiv, 10.26434/chemrxiv-2022-0c1s7 (2022).

23. Di- and Trinuclear Complexes of Pd(0) and Pt(0) with Bridging Silylene Ligands: Structures with a Coordinatively Unsaturated Metal Center and Their Reactions with Alkynes
Makoto Tanabe,* Yu Nakamura, Taka-aki Niwa, Masaru Sakai, Akira Kaneko, Hiroyuki Toi, Kazuki Okuma, Yoshitaka Tsuchido, Take-aki Koizumi, Kohtaro Osakada,* and Tomohito Ide
Organometallics, 41(22), 3301-3312, (2022).

22. Dynamic Au-C σ-Bonds Leading to an Efficient Synthesis of [n]Cycloparaphenylenes (n = 9 - 15) by a Self-Assembly
Yusuke Yoshigoe,* Yohei Tanji, Yusei Hata, Kohtaro Osakada, Shinichi Saito, Eiichi Kayahara, Shigeru Yamago, YoshitakaTsuchido,* Hidetoshi Kawai*
JACS Au, 2(8), 1857-1868 (2022). Selected as a "Cover"
Tokyo Univ. Sci. Press Release


21. Digold(I) Thianthrenyl Complexes. Effect of Diphosphine Ligands on Molecular Structures in the Solid State and in Solution
Ryota Abe, Yoshitaka Tsuchido,* Tomohito Ide, Take-aki Koizumi, Kohtaro Osakada*
ACS Omega, 7(11), 9594-9601, (2022).

20. Cyclic and linear dithienyl-anthryl vinylenes: synthesis, X-ray crystallography, spectroscopic properties, and photoinduced mechanical motions
Pin-Rong Wu, Chi-Hsien Wang, Yi-Wen Chen, Yen-Jen Lin, Tomohito Ide, Yoshitaka Tsuchido, Yoshihisa Sei, Masaki Horie*
J. Mater. Chem. C, 10(11), 4306-4316, (2022).

2021

19. Spacer-Dependent Cooperativity of Helicity in Fluorescent Bishelical Foldamers Based on L-shaped Dibenzopyrrolo[1,2-a][1,8]naphthyridine
Kotaro Matsumura, Kotaro Tateno, Yoshitaka Tsuchido, Hidetoshi Kawai*
ChemPlusChem, 86(10), 1421-1425 (2021).

18. Sulphur-Embedded Hydrocarbon Belts: Synthesis, Structure and Redox Chemistry of Cyclothianthrenes
Shenghua Wang, Jun Yuan, Jialin Xie, Zonghuan Lu, Long Jiang, Yingxiao Mu, Yanping Huo, Yoshitaka Tsuchido, Kelong Zhu*
Angew. Chem. Int. Ed., 60(34), 18443-18447, (2021).

17. Ring rotation of ferrocene in interlocked molecules in single crystals
Chi-Hsien Wang, Kai-Jen Chen, Tsung-Huan Wu, Hung-Kai Chang, Yoshitaka Tsuchido, Yoshihisa Sei, Pei-Lin Chene, Masaki Horie*
Chem. Sci., 12(11), 3871-3875, (2021). Edge Article

2020

16. Photoinduced Mechanical Motions of Pseudorotaxane Crystals Composed of Azobenzene and Ferrocenyl Groups on an Axle and a Crown Ether Ring
Shao-Chi Cheng, Chi-Hsien Wang, Yi-Chia Lin, Yoshitaka Tsuchido, Yuji Suzaki, Yoshihisa Sei, Ting-Shen Kuo, Masaki Horie*
ACS Appl. Mater. Interfaces, 12(44), 50002-50010, (2020).

15. Macrocyclic Gold(I)‐biphenylene Complex: Triangular Molecular Structure with Twisted Au2(diphosphine) Corners and Reductive Elimination of [6]Cycloparaphenylene
Yoshitaka Tsuchido,* Ryota Abe, Tomohito Ide, Kohtaro Osakada*
Angew. Chem. Int. Ed., 59(51), 22928-22932, (2020).

14. Transformation of Thiolatogold(I) to an Au Complex with an (Arylthio)silyl Ligand. Use of an (Aminosilyl)boronic Ester as a Silylene Precursor
Yoshitaka Tsuchido, Kazuki Okuma, Tomohito Ide,* Kohtaro Osakada*
Organometallics, 39(14), 2565-2569, (2020).

13. Structure and properties of lantern‐shaped hexapalladium complexes with germylene and thiolate ligands [Pd6(μ-GePh2)(μ-SC6H4-p-X)(CN-C6H3Me2-2,6)8] (X = NO2, Cl, H, CH3)
Take-aki Koizumi,* Yoshitaka Tsuchido, Tomohito Ide, Kohtaro Osakada*
Eur. J. Inorg. Chem., 2253-2259, (2020).

12. Gold(I) complexes with chloro(diaryl)silyl ligand. Stoichiometric reactions and catalysis for O-functionalization of organosilane
Yoshitaka Tsuchido, Atsushi Kanda, Kohtaro Osakada*
Tetrahedron, 76(15), 131076, (2020).

2019

11. Bimolecular fusion of [Pd3(μ-CN-C6H3Me2-2,6)3(CN-C6H3Me2-2,6)3] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex
Take-aki Koizumi, Kimiya Tanaka, Yoshitaka Tsuchido, Makoto Tanabe, Tomohito Ide, Kohtaro Osakada*
Dalton Trans., (48), 7541-7545, (2019).

10. Synthesis and Aggregation Behavior of Poly(arylene alkenylene)s and Poly(arylene alkylene)s Having Dialkoxyphenylene and Aromatic Diimide Groups
Li Yi Tan, Yoshitaka Tsuchido, Kohtaro Osakada, Zhengguo Cai, Yoshiaki Takahashi, Daisuke Takeuchi*
Macromolecules, 52(4), 1642-1652, (2019).

9. Pd-catalyzed Sonogashira coupling in aqueous media. Observation of micelles that contain substrates and catalyst
Yuji Suzaki, Yuka Kobayashi,Yoshitaka Tsuchido, Kohtaro Osakada*
Mol. Catal., 466, 106-111, (2019).

2018

8. Hydrosilylation of Aromatic Aldehydes and Ketones Catalyzed by Mono- and Tri-Nuclear Platinum(0) Complexes
Yoshitaka Tsuchido, Ryota Abe, Megumi Kamono, Kimiya Tanaka, Makoto Tanabe, Kohtaro Osakada*
Bull. Chem. Soc. Jpn., 91(5), 858-864, (2018).

7. Reversible Laser-Induced Bending of Pseudorotaxane Crystals
Shao-Chi Cheng, Kai-Jen Chen, Yuji Suzaki, Yoshitaka Tsuchido, Ting-Shen Kuo, Kohtaro Osakada, Masaki Horie*
J. Am. Chem. Soc., 140(1), 90-93, (2018).

2015

6. 1,4-Selective Diels-Alder Reaction of 9,10-Diethynylanthracene with 3,6-Difluorobenzyne
Yoshitaka Tsuchido, Tomohito Ide, Yuji Suzaki, Kohtaro Osakada*
Bull. Chem. Soc. Jpn., 88(6), 821-823, (2015).

2014

5. Dynamic Properties of Molecular Tweezers with a Bis(2-hydroxyphenyl)pyrimidine Backbone
Yoshitaka Tsuchido, Yuji Suzaki, Tomohito ide, Kohtaro Osakada*
Chem. Eur. J., 20(16), 4762-4771, (2014)

2012

4. Improvement of Thermal Stability of Gold Nanoparticles by Synergistic Interligand Interactions
Atsushi Okumura, Yoshitaka Tsuchido, Kou Yamada, Kenji Todori, Shigeru Machida*
Chem. Lett., 41(7), 708-710, (2012).

2011

3. [3]Rotaxane-Based Dinuclear Palladium Catalysts for Ring-closure Mizoroki-Heck Reaction
Yuji Suzaki, Kyoichi Shimada, Eriko Chihara, Takashi Saito, Yoshitaka Tsuchido, Kohtaro Osakada*
Org. Lett, 13(15), 3774-3777, (2011).

2. Tweezers-like Aromatic Molecules and Their Luminescent Properties Depending on the Structures
Yuji Suzaki,Yoshitaka Tsuchido, Kohtaro Osakada*
Tetrahedron Lett., 52(30), 3883-3885, (2011).

2010

1. Development of Thermally-resistant Gold Nanoparticles
Yoshitaka Tsuchido, Kou Yamada, Kenji Todori, Shigeru Machida*
Trans. Mater. Res. Soc. Jpn., 35(2), 271-274, (2010).

総説・解説・記事

4. 動的な金-炭素結合が織りなす分野融合化学 大環状金錯体からナノフープ合成への展開
土戸良高*
科学フォーラム, 448(8), 4-7, (2025).

3. シクロパラフェニレンを基盤とした超分子化学の展開
土戸良高*
化学と工業, 77(5), 344-345, (2024).

2. シクロパラフェニレンの超分子化学
土戸良高*
超分子研究会アニュアルレビュー, 43, 10-11, (2022).

1. Multinuclear Pd and Pt complexes with bridging Si- and Ge-ligands. Stable and flexible coordination bonds and structures and reactions of the molecules
Kohtaro Osakada*, Yoshitaka Tsuchido, Makoto Tanabe
Coord. Chem. Rev., 412(1), 213195, (2020).


受 賞

2025年3月
日本化学会第105春季年会 若い世代の特別講演 講演証

2025年2月
2024年度 有機合成化学奨励賞
  「Au(I)-C結合を利用したシクロパラフェニレン類の革新的合成法の開発」

2018年12月
2018年有機合成化学協会 関東化学研究企画賞

2018年12月
第28回日本MRS年次大会 奨励賞

2014年10月
第15回リング・チューブ超分子研究会シンポジウム ポスター賞

2014年3月
第14回リング・チューブ超分子研究会シンポジウム ポスター賞

2013年7月
ACS Poster Award, 8 th International Symposium on Macrocyclic and Supramolecular Chemistry

2013年3月
日本化学会第93春季年会 学生講演賞

2012年9月
第23回基礎有機化学討論会 ポスター賞

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