List of Publications
Academic papers
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カルコゲン結合を利用した触媒反応ー珍しい相互作用による新しい有機合成
荻原陽平, 坂井教郎
化学(化学同人) 2019, 74, 66-67. (最新のトピックス)
Sulfenylation of arenes and olefins with acidic sulfenamides
Shimizu, M.; Suzuki, S.; Tanaka, S.; Ando, W.; Sakai, N.
Phosphorus, Sulfur, Silicon, Relat. Elem. 2019, 194, 764-767. (proceeding)
DOI: 10.1080/10426507.2019.1603724
Catalytic C–H/C–F Coupling of Azoles and Acyl Fluorides
Ogiwara, Y,; Iino, Y.; Sakai, N.
Chem Eur. J. 2019, 25, 6513-6516.
Selected as Most Downloaded Paper in 2018-2019
Copper-Catalyzed Three-Component Coupling Reaction of Aryl Iodides, a Disilathiane, and Alkyl Benzoates Leading to a One-Pot Synthesis of Alkyl Aryl Sulfides
Sakai, N.; Maeda, H.; Ogiwara, Y.
Synthesis 2019, 51, 2323-2330.
Palladium(II)/Copper(II)-Catalyzed C-H Sulfidation or Selenation of Arenes Leading to Unsymmetrical Sulfides and Selenides
Nishino, K.; Tsukahara, S.; Ogiwara, Y.; Sakai, N.
Eur. J. Org. Chem. 2019, 1588-1593.
Selected as Most Downloaded Paper in 2018-2019
2019
citation number (over 50) searched by SciFinder
6.2.2020 Update
2019~2015
Construction of N-Heterocyclic Systems Containing a Fully
Substituted Allylic Carbon by Palladium/Phosphine Catalysis
Ogiwara, Y.; Suzuki, Y.; Sato, K.; Sakai, N.
Org. Lett. 2018, 20, 6965-6969.
DOI: 10.1021/acs.orglett.8b03127
Group-4-Metallocene-Difluoride/Palladium Bimetallic Catalysts for the
Reductive Cross-Coupling of Alkynes with Aryl Iodides and Bromides
Takahashi, K.; Morishita, H.; Ogiwara, Y.; Sakai, N.
J. Org. Chem. 2018, 83, 13734-13742.
Palladium-Catalyzed Reductive Conversion of Acyl Fluorides via
Ligand-Controlled Decarbonylation
Ogiwara, Y.; Sakurai, Y.; Hattori, H.; Sakai, N.
Org. Lett. 2018, 20, 4204-4208.
DOI: 10.1021/acs.orglett.8b01582
Palladium(II)-Catalyzed Synthesis of Dibenzothiophenes from
2-Biphenylyl Disulfides via C-H functionalization
Nishino, K.; Ogiwara, Y.; Sakai, N.
Chem. Eur. J. 2018, 24, 10971-10974.
Indium-Catalyzed Direct Conversion of Lactones into Thiolactones Using
a Disilathiane as a Sulfur Source
Ogiwara, Y.; Takano, K.; Horikawa, S.; Sakai, N.
Molecules (Special Issue) 2018, 23, 1339-1349.
DOI: 10.3390/molecules23061339 (open access)
Indium-catalyzed Direct Conversion of Dibenzyl Ethers to Dibenzyl
Sulfides Using Elemental Sulfur and a Hydrosilane and Its Application to
the Preparation of Benzyl Selenides
Sakai, N.; Takada, K.; Katayama, M.; Ogiwara, Y.
Chem. Lett. 2018, 47, 791-793.
DOI: 10.1246/cl.180242
Palladium-Catalyzed Reductive Coupling Reaction of Terminal Alkynes
with Aryl Iodides Utilizing Hafnocene Difluoride as a Hafnium Hydride
Precursor Leading to trans-Alkenes
Takahashi, K.; Ogiwara, Y.; Sakai, N.
Chem. Asian J. 2018, 13, 809-814.
Indium-Catalyzed Direct Conversion of Lactones into Thiolactones and
Selenolactones in the Presence of Elemental Sulfur and Selenium
Sakai, N.; Horikawa, S.; Ogiwara, Y.
Synthesis 2018, 50, 565-574.
Copper-Catalyzed Production of Daryl Sulfides Using Aryl Iodides and
a Disilathiane
Ogiwara, Y.; Maeda, H.; Sakai, N.
Synlett 2018, 29, 655-657.
DOI: 10.1055/s-0036-1591723 as Thieme News-Archive 2017
インジウム触媒とヒドロシランを用いた還元的分子変換を中心とする有機合成
(Indium-Catalyzed Reductive Molecular Transformation Using Hydrosilanes)
荻原陽平, 坂井教郎
有機合成化学協会誌 2018, 76, 21-36.
2018
One-pot Two-step Conversion of Aromatic Carboxylic Acids and Esters
to Aromatic Aldehydes Via Indium-Catalyzed Reductive
Thioacetalization and Desulfurization
Sakai, N.; Minato, K.; Ogiwara, Y.
Tetrahedron Lett. 2017, 58, 4563-4567.
DOI: 10.1016/j.tetlet.2017.10.050
Copper-Catalyzed Cyanation of Aryl Iodides Using Nitromethane
Ogiwara, Y.; Morishita, H.; Sasaki, M.; Imai, Y.; Sakai, N.
Chem. Lett. 2017, 46, 1736-1739.
DOI: 10.1246/cl.170798
Palladium-Catalyzed Intramolecular Cyclization of Alkynoic Acids To
Form Vinyl Dioxanones Bearing a Quaternary Allylic Carbon
Ogiwara, Y.; Sato, K.; Sakai, N.
Org. Lett. 2017, 19, 5296-5299.
DOI: 10.1021/acs.orglett.7b02572
Green Preparation of Dibenzothiophene Derivatives Using 2-Biphenylyl
Disulfides in the Presence of Molecular Iodine and Its Application
to Dibenzoselenophene Synthesis
Nishino, K.: Ogiwara, Y.; Sakai, N.
Eur. J. Org. Chem. 2017, 5892-5895.
Acid Fluorides as Acyl Electrophiles in Suzuki-Miyaura Coupling
Ogiwara, Y.; Sakino, D.; Sakurai, Y.; Sakai, N.
Eur. J. Org. Chem. 2017, 4324-4327.
Indium-Catalyzed Reductive Dithioacetalization of Carboxylic Acids with
Dithiols: Scope, Limitations, and Application to Oxidative Desulfurization
Nishino, K.: Minato, K.: Miyazaki, T.: Ogiwara, Y.; Sakai, N.
J. Org. Chem. 2017, 82, 3659-3665.
Reaction of 2-alkylidene-3,1-benzoxathiin-4-ones with nitrones
Shimizu, M.; Yamanaka, M.; Kurita, K.; Tanaka, S.; Ando, W.; Sakai, N.
Phosphorus, Sulfur, Silicon, Relat. Elem. 2017, 192, 249-251. (proceeding)
DOI: 10.1080/10426507.2016.1255620
Cyclization of 2-(N-pyrrolylsulfenyl)benzoic acids for the synthesis of
pyrrolo[1,2-b][1,2]benzothiazin-10-ones
Masuda, K.; Kato, D.; Tanaka, S.; Ando, W.; Sakai, N.; Shimizu, M.
Phosphorus, Sulfur, Silicon, Relat. Elem. 2017, 192, 235-236. (proceeding)
DOI: 10.1080/10426507.2016.1255618
Carboxamides as an N-Alkylating Reagent of Secondary Amines in
Indium-Catalyzed Reductive Amination with a Hydrosilane
Ogiwara, Y.; Shimoda, W.; Ide, K., Nakajima, T.; Sakai, N.
Eur. J. Org. Chem. 2017, 2866-2870.
Selected as Very Important Paper (VIP) and Cover Picture of EurJOC
Determination of binding modes and binding constants for the
complexes of 6H-pyrido[4,3-b]carbazole derivatives with DNA
Shimazu, A.: Kawagoshi, M.; Takeda, S.; Kurasaki, H.; Kato, A.; Morii, N.;
Sakai, N.; Konakahara, T.
Bioorg. Med. Chem. 2017, 25, 1094-1112.
DOI: 10.1016/j.bmc.2016.12.031
Indium-Catalyzed Reduction of a Nitroarene Using a Hydrosilane:
A Selective Reduction Strategy for the Efficient Synthesis of Indoprofen
Ogiwara, Y.; Sakurai, Y.; Sakai, N.
Chem. Lett. 2017, 46, 240-242.
DOI: 10.1246/cl.161008
One-Pot Preparation of Pyrrole Derivatives via the Copper-Catalyzed
[4+1] Annulation of Propargylic Amines with Ethyl Glyoxylate and
Phenylglyoxal in the Presence of Piperidine
Sakai, N.; Suzuki, H.; Hori, H,; Ogiwara, Y.
Tetrahedron Lett. 2017, 58, 63-66.
DOI: 10.1016/j.tetlet.2016.11.097
Cobalt(II)–Catalyzed Oxidative Coupling of Aromatic Tertiary Amines
with Enol Silyl Ethers Leading to β-Aminoketone Derivatives
Sakai, N.; Muraoka, T.; Matsumoto, S.; Mutsuro, A.; Ogiwara, Y.
Synlett 2017, 28, 343-346.
2017
2016
Cobalt-Catalyzed Oxidative Annulation of Aromatic Tertiary Amines with
Electron-Deficient Maleimides Leading to Tetrahydroquinoline Derivatives
Sakai, N.; Matsumoto, S.; Ogiwara, Y.
Tetrahedron Lett. 2016, 57, 5449-5452.
DOI: 10.1016/j.tetlet.2016.10.071
Gallium-Catalyzed Reductive Lactonization of γ-Keto Acids with
a Hydrosilane
Sakai, N.; Horikawa, S.; Ogiwara, Y.
RSC Adv. 2016, 6, 81763-81766.
DOI: 10.1039/C6RA19286F
Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion
of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation
Ogiwara, Y.; Ono, Y.; Sakai, N.
Synthesis, 2016, 48, 4143-4148.
Indium-Catalyzed Reductive Three-Component Coupling Reaction of
Aliphatic/Aromatic Carboxylic Acids with t-Butyl Mercaptan Leading to
Unsymmetrical Dialkyl Sulfides
Sakai, N.; Yoshimoto, S.; Miyazaki, T.; Ogiwara, Y.
Tetrahedron Lett. 2016, 57, 3117-3120.
DOI: 10.1016/j.tetlet.2016.06.001
Synthesis and Cytotoxic Activity of Novel 11-Methyl-6H-Pyrido[4,3-b]
Carbazole Derivatives Linked to Amine, N-Methylurea, and
N-Methyl-N-Nitrosourea Moieties with Various Types of Carbamoyl
Tethers at the C-5 Atom
Kato, A.; Nagatsuka, Y.; Hiratsuka, T.; Kiuchi, S.; Iwase, Y.; Okuno, Y.;
Tsukamoto, T.; Kiran, Y. B.; Sakai, N.; Konakahara, T.
Tetrahedron 2016, 72, 4258-4272.
DOI: 10.1016/j.tet.2016.05.068
Palladium-Catalyzed Coupling of Benzoyl Halides with Aryltrifluorosilanes
Leading to Diaryl Ketones
Ogiwara, Y.; Maegawa, Y.; Sakino, D.; Sakai, N.
Chem. Lett. 2016, 45, 790-792.
DOI: 10.1246/cl.160223
Copper-Catalyzed [3+2] Annulation of Propargylic Acetates with Anilines
in the Presence of Trimethylsilyl Chloride Leading to 2,3-disubstituted
Indoles via an Aza-Claisen Rearrangement
Sakai, N.; Enomoto, K.; Takayanagi, M.; Konakahara, T.; Ogiwara, Y.
Tetrahedron Lett. 2016, 57, 2175-2178.
DOI: 10.1016/j.tetlet.2016.04.007
Production of Quaternary α-Aminonitriles by Means of Indium-Catalyzed
Three-Component Reaction of Alkynes, Amines, and Trimethylsilyl
Cyanide
Hamachi, Y.; Katano, M.; Ogiwara, Y.; Sakai, N.
Org. Lett. 2016, 18, 1634-1637.
DOI: 10.1021/acs.orglett.6b00508
Synthesis and in vitro Antitumor Activity of 9-Hydroxyellipticine
Derivatives with Glucose Conjugation via Triazolylmethyl Succinate
Linker
Sato, N.; Kawai, Y.; Akaba, Y.; Honma, S.; Sakai, N.; Konakahara, T.
Heterocycles 2016, 92, 664-679.
DOI: 10.3987/COM-16-13404
Indium-Catalyzed Reductive Sulfidation of Esters by Using Thiols:
An Approach to the Diverse Synthesis of Sulfides
Miyazaki, T.; Kasai, S.; Ogiwara, Y.; Sakai, N.
Eur. J. Org. Chem. 2016, 1043-1049.
Indium-Catalyzed Direct Preparation of Dibenzyl Sulfides from Benzyl
Alcohols and Elemental Sulfur with a Hydrosilane and Its Application to
the Preparation of Dibenzyl Selenide
Miyazaki, T.; Katayama, M.; Yoshimoto, S.; Ogiwara, Y.; Sakai, N.
Tetrahedron Lett. 2016, 57, 676-679.
DOI: 10.1016/j.tetlet.2015.12.109
Reductive Amination/Cyclization of Keto Acids Using a Hydrosilane for
Selective Production of Lactams versus Cyclic Amines by Switching of
the Indium Catalyst
Ogiwara, Y.; Uchiyama, T.; Sakai, N.
Angew. Chem. Int. Ed. 2016, 55, 1864-1867.
DOI: 10.1002/anie.201509465 (61 citation number by Sep 2020)
Oxidative Coupling of Terminal Alkynes with Aldehydes Leading to
Alkynyl Ketones by Using Indium(III) Bromide
Ogiwara, Y.; Kubota, M.; Kurogi, K.; Konakahara, T.; Sakai, N.
Chem. Eur. J. 2015, 21, 18598-18600.
Cited by SYNFACTS 2015, 12, 0188-0188
Indium-Catalyzed Reduction of Secondary Amides with a Hydrosiloxane
Leading to Secondary Amines
Sakai, N.; Takeoka, M.; Kumaki, T.; Asano, H.; Konakahara, T.; Ogiwara, Y.
Tetrahedron Lett. 2015, 56, 6448-6451.
DOI: 10.1016/j.tetlet.2015.09.148
One-pot Synthesis of Tetralin Derivatives From 3-Benzoylpropionic Acids:
Indium-Catalyzed Hydrosilylation of Ketones and Carboxylic Acids and
Intramolecular Cyclization
Sakai, N.; Kobayashi, T.; Ogiwara Y.
Chem. Lett. 2015, 44, 1503-1505.
DOI: 10.1246/cl.150686
Indium(III)-Catalyzed Reduction of Nitrobenzenes to Anilines: Scope and
Limitations
Sakai, N.; Asama, S.; Konakahara, T.; Ogiwara, Y.
Synthesis 2015, 47, 3179-3185.
2価パラジウム錯体からの還元的脱離によるsp2 炭素-ハロゲン結合形成と
最近の展開
荻原陽平
有機合成化学協会誌 2015, 73, 1020-1021. (Review de Debut)
DOI: 10.5059/yukigoseikyokaishi.73.1020
Copper(II)-Catalyzed Oxidative Nitrosation of Secondary and Tertiary Amines with Nitromethane Under an Oxygen Atmosphere
Sakai, N.; Sasaki, M.; Ogiwara, Y.
Chem. Commun. 2015, 51, 11638-11641.
DOI: 10.1039/C5CC03675E
A Novel Macroreticular-Type Fluorous Polystyrene Resin and Its
Application to the Synthesis of a 3-Amino-β-Carboline Derivative with
N-Methyl-N-Nitrosourea Conjugation via Fluorous Solid-Phase Reaction:
A Comparative Study of Fluourous-Solid, Solid-, and Liquid-Phase
Reactions
Suzuki, K.; Kumagai, M.; Utsunomiya, M.; Sakai, N.; Konakahara, T.
Tetrahedron 2015, 71, 4999-5012.
DOI: 10.1016/j.tet.2015.05.072
Copper(I)-Catalyzed Coupling Reaction of Aryl Boronic Acids with N,O-
Acetals and N,N-Aminals Under Atmosphere Leading to α-Aryl Glycine
Derivatives and Diarylmethylamine Derivatives
Sakai, N.; Hori, H.; Yoshida, Y.; Konakahara, T.; Ogiwara, Y.
Tetrahedron 2015, 71, 4722-4729.
DOI: 10.1016/j.tet.2015.05.068
Indium(III)-Catalyzed Reductive One-Pot Synthesis of Thioethers from
Aromatic Aldehydes and Elemental Sulfur
Miyazaki, T.; Nishino, K.; Konakahara, T.; Sakai, N.
Phosphorus, Sulfur, Silicon, Relat. Elem. 2015, 190, 1378-1379.
(proceeding)
DOI: 10.1080/10426507.2015.1036990
Indium(III)-Catalyzed Knoevenagel Condensation of Aldehydes and
Activated Methylenes Using Acetic Anhydride as a Promoter
Ogiwara, Y.; Takahashi, K.; Kitazawa, T.; Sakai, N.
J. Org. Chem. 2015, 80, 3101-3110.
Indium(III)-Catalyzed Reductive Monoalkylation of Electron-Rich
Benzenes with Aliphatic Carboxylic Acids Leading to Arylalkane
Derivatives
Moriya, T.; Takayama, K.; Konakahara, T.; Ogiwara, Y.; Sakai, N.
Eur. J. Org. Chem. 2015, 2277-2281.
Copper(II)-Catalyzed [4+1] Annulation of Propargylamines with N,O-
Acetals: Entry to the Synthesis of Polysubstituted Pyrrole Derivatives
Sakai, N.; Hori, H.; Ogiwara, Y.
Eur. J. Org. Chem. 2015, 1905-1909.
Indium-Catalyzed Reductive Sulfidation of Aromatic Carboxylic Acids and
Aldehydes with Elemental Sulfur to Prepare Symmetrical Benzyl Sulfides
Miyazaki, T.; Nishino, K.; Yoshimoto, S.; Ogiwara, Y.; Sakai, N.
Eur. J. Org. Chem. 2015, 1991-1994.
One-Pot Preparation of Alkyl Iodides from Esters by Indium-Catalyzed
Reductive Cleavage of a Carbon-Oxygen Bond
Sakai, N.; Matsushita, Y.; Konakahara, T.; Ogiwara, Y.; Hirano, K.
Eur. J. Org. Chem. 2015, 1591-1595.
2015
